Simultaneous connections to the internet or a Windows domain must be limited.
Multiple network connections can provide additional attack vectors to a system and must be limited. The "Minimize the number of simultaneous connections to the Internet or a Windows Domain" setting prevents systems from automatically establishing multiple connections. When both wired and wireless connections are available, for example, the less preferred connection (typically wireless) will be disconnected.
How this relates to the STIG checklist: STIG vs SCAP benchmark.